Bayram O.20.04.20192019-04-2020.04.20192019-04-2020180272-8842https://dx.doi.org/10.1016/j.ceramint.2018.08.055https://hdl.handle.net/20.500.12403/338In this study, synthesis and characterization of plasma polymerized Thiophene/ Nickel doped Zinc Oxide (PTNZO) bilayer nanocomposite films were carried out. Nickel doped zinc oxide (NZO) thin films were obtained by magnetron sputtering technique on glass substrates at 40 W Radio Frequency (RF) power. Plasma polymerized Thiophene (PT) thin films were deposited on the NZO thin films obtained on the glass substrate by Radio Frequency (RF) plasma polymerisation technique. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), FTIR and Photoluminescence (PL) analyzes were performed for the characterization of PTNZO hetero bilayer nanocomposite films. In the XRD spectra of PTNZO bilayer nanocomposite thin films, (002) planes were determined as the most basic peak, and it was determined that the intensity of this peak, changed depending on the RF power of polymer thin films. Optical properties of nanocomposite thin films such as transmittance, absorbance and optical band gap were determined by UV–Vis spectroscopy. Optical band gap for PTNZO nanocomposites were 2.72 eV, 2.34 eV, and 2.45 eV, respectively, with increasing RF power. For NZO thin films, this value is 3.12 eV. The optical band gaps calculated from the absorption and transmittance spectra obtained using UV–visible spectroscopy had a good compatibility with those of the optical band spectra calculated from the PL spectra. The tetragonal wurtzite structure of the NZO thin films was examined by SEM analysis. The grain size of NZO nanostructure was found to be approximately 59 nm. © 2018 Elsevier Ltd and Techna Group S.r.l.eninfo:eu-repo/semantics/closedAccessBilayer nanocompositeConjugated polymersThiopheneWurtzite structureZnOConjugated polymersEnergy gapFourier transform infrared spectroscopyGlassII-VI semiconductorsNanocomposite filmsNanocompositesNickel oxideOptical band gapsOptical propertiesOxide filmsPhotoluminescencePlasma polymerizationPolymer filmsRadio wavesScanning electron microscopySubstratesThin filmsThiopheneX ray diffractionZinc oxideZinc sulfideBi-layerNanocomposite thin filmsPhotoluminescence propertiesRadio frequency plasmaRadio frequency powerSynthesis and characterizationsTransmittance spectraWurtzite structureOptical filmsBilayer nanocompositeConjugated polymersThiopheneWurtzite structureZnOConjugated polymersEnergy gapFourier transform infrared spectroscopyGlassII-VI semiconductorsNanocomposite filmsNanocompositesNickel oxideOptical band gapsOptical propertiesOxide filmsPhotoluminescencePlasma polymerizationPolymer filmsRadio wavesScanning electron microscopySubstratesThin filmsThiopheneX ray diffractionZinc oxideZinc sulfideBi-layerNanocomposite thin filmsPhotoluminescence propertiesRadio frequency plasmaRadio frequency powerSynthesis and characterizationsTransmittance spectraWurtzite structureOptical filmsArticle4417206352064010.1016/j.ceramint.2018.08.0552-s2.0-85051394658Q1WOS:000448226900004Q1