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Synthesis, characterization and complexation properties of a novel Mg-porphyrazine with metal ions in acetonitrile-chloroform

Date

2015

Author

Kabay N.
Baygu Y.
Gök Y.
Başo?lu A.
Ocak U.

Metadata

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Abstract

The synthesis and characterization of a novel metal derivative of a peripherally symmetrically tetra-substituted porphyrazine derived from 25,26-dioxa-6,7,9,10,15,16,18,19-octahydro-25H-1,24-methanodibenzo[q,t][1,4,13,16,17,10]tetraoxadithiacyclohenicosine-12,13-dicarbonitrile was carried out. The influence of metal cations such as Zn2+, Fe2+, Mn2+, Ni2+, Co2+, Hg2+ and Cu2+ on the spectroscopic properties of the ligands, the starting material dinitrile and MgPz were investigated in acetonitrile-chloroform solution (1/1) by means of absorption spectrometry. Absorption spectra showed isosbestic points in the spectrophotometric titration of Cu2+ and Hg2+ with MgPz ligand. The results of spectrophotometric titration experiments disclosed the complex stability constant of the novel ligand, MgPz with Cu2+ and Hg2+ cations.

Source

Main Group Chemistry

Volume

14

Issue

1

URI

https://dx.doi.org/10.3233/MGC-140148
https://hdl.handle.net/20.500.12403/755

Collections

  • Scopus İndeksli Yayınlar Koleksiyonu [570]
  • WoS İndeksli Yayınlar Koleksiyonu [372]



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