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Öğe Achieving room temperature superplasticity in Zn-5Al alloy at high strain rates by equal-channel angular extrusion(Elsevier Ltd, 2015) Demirtas M.; Purcek G.; Yanar H.; Zhang Z.J.; Zhang Z.F.Multi-pass equal-channel angular extrusion/pressing (ECAE/P) was applied to the eutectic Zn-5Al alloy to achieve high strain-rate (HSR) superplasticity in that alloy at room temperature (RT) by producing ultrafine-grained (UFG) microstructure. ECAE processing transformed the coarse-grained lamellar/spherical microstructure into a unique bimodal structure having equiaxed Zn-rich ?-phase with a mean grain size of 540 nm and spherical Al-rich ?-phase with an average grain size of 110 nm. The ?-phase particles accumulated mainly along the ?-phase boundaries. This unique microstructure brought about an extraordinary improvement in HSR superplasticity of the alloy even at RT. While the strength values decreased after ECAE, the elongation to failure increased substantially. The maximum elongation was 520% at the strain rate of 10-3 s-1, still high elongation of about 400% was achieved at a high strain rate of 10-2 s-1. This extraordinary improvement in HSR superplasticity of Zn-5Al alloy was attributed to the morphologically unique bimodal microstructure in UFG regime formed after ECAE. The grain boundary sliding (GBS) was found to be the main deformation mechanism for this alloy in superplastic regime. © 2014 Elsevier B.V.Öğe Effect of different processes on lamellar-free ultrafine grain formation, room temperature superplasticity and fracture mode of Zn-22Al alloy(Elsevier Ltd, 2016) Demirtas M.; Purcek G.; Yanar H.; Zhang Z.J.; Zhang Z.F.The Zn-22 wt.%Al was processed using five different selected routes including thermal, thermo-mechanical and severe plastic deformation (SPD) techniques in order to produce ultrafine grained (UFG) microstructure for achieving room temperature (RT) and high strain rate (HSR) superplasticity, and to compare the same set of the results. After all routes, the microstructural evolutions and RT uniaxial tensile tests at different strain rates ranging from 1 × 10-3 to 1 × 100 s-1 were investigated. The smallest grain size was achieved to be 300 nm after the thermo-mechanical process including conventional hot and cold rolling steps. However, the lamellar microstructure of the alloy was not completely eliminated during that process. On the other hand, equal-channel angular pressing (ECAP) as one of the SPD techniques decreased the grain size down to 400 nm with a lamellar-free microstructure. The maximum elongation value was achieved to be 330% with the sample tested at 1 × 10-3 s-1 after a thermo-mechanical process including conventional hot and cold rolling, and an aging stage between these rolling steps. It was found that lamellar-free microstructure causes higher superplastic elongation even if it has higher grain size compared to the sample having partially lamellar structure. © 2015 Elsevier B.V.Öğe Effect of equal-channel angular pressing on room temperature superplasticity of quasi-single phase Zn-0.3Al alloy(Elsevier Ltd, 2015) Demirtas M.; Purcek G.; Yanar H.; Zhang Z.J.; Zhang Z.F.Quasi-single phase (dilute) Zn-0.3Al alloy was subjected to severe plastic deformation via equal-channel angular extrusion/pressing (ECAE/P), and the effects of ECAP on its room temperature (RT) and high strain rate (HSR) superplasticity and deformation mechanism were investigated. Multi-pass ECAP may refine the coarse-grained microstructure into the fine grained (FG) one. The grain size of Zn-matrix phase decreased down to 2.0m after ECAP. Many spherical Al-rich precipitates decomposed and homogeneously distributed inside the matrix phase. They are ultrafine grained (UFG) ?-particles with the grain sizes ranging from 50nm to ~200nm. This special microstructure having FG and UFG micro-constituents brought about an improvement in RT superplasticity even at HSRs. While multi-pass ECAP decreased flow stress of the alloy, its elongation to failure increased substantially depending on the initial strain rates. The maximum elongation was 1000% at a low strain rate of 10-4s-1, and 350% elongation was achieved at a high strain rate of 10-2s-1. Grain boundary sliding (GBS) was found to be the main deformation mechanism in region-II as the optimum superplastic region. © 2015 Elsevier B.V..Öğe Effect of grain refinement and phase composition on room temperature superplasticity and damping capacity of dual-phase Zn-Al alloys(Cambridge University Press, 2018) Demirtas M.; Atli K.C.; Yanar H.; Purcek G.The effects of grain refinement and phase composition on superplasticity and damping capacity of eutectic Zn-5Al and eutectoid Zn-22Al alloys were investigated. For grain refinement, equal-channel angular pressing (ECAP) was applied to these alloys. ECAP completely eliminated the as-cast lamellar microstructures of both alloys and resulted in ultrafine-grained structures along with room temperature superplasticity. Furthermore, these microstructural changes with ECAP increased the damping capacity of both alloys in the dynamic hysteresis region, where damping arises from viscous sliding of phase/grain boundaries. Dynamic recrystallization at the surface and thermally activated viscous motion of grain/phase boundaries at the subsurface of the samples of both alloys were proposed as the damping mechanisms in the region where the alloys showed combined aspects of static/dynamic hysteresis damping behavior. Although the grain size is larger in Zn-5Al compared to Zn-22Al, it showed higher damping capacity due to the different sliding characteristics of its phase boundaries. © 2018 Materials Research Society.Öğe Effect of natural aging on RT and HSR superplasticity of ultrafine grained Zn-22Al alloy(Trans Tech Publications Ltd, 2016) Demirtas M.; Purcek G.; Yanar H.; Zhang Z.; Zhang Z.-F.Zn–22Al alloy was processed using a well-designed two-step equal channel angular extrusion/pressing (ECAE/P), and ultrafine-grained (UFG) microstructure with 200 nm grain size was achieved. UFG Zn-22Al was subjected to long-term (up to 60 days) aging at room temperature (RT) and it was seen that natural aging caused limited grain growth in the microstructure. Grain sizes of about 300 nm, 350 nm and 350 nm were measured after 15, 30 and 60 days aging, which mean that UFG Zn-22Al alloy has a good microstructural stability at RT up to 60 days. ECAPed Zn-22Al alloy showed a maximum elongation of about 400% at a high strain rate of 5×10-2 s-1 and maximum elongation decreased with increasing grain size. Elongation to failures of ~375% and ~350% were obtained with the samples having 300 nm and 350 nm grain sizes, respectively. In addition, natural aging slightly decreased the strain rate at which superplastic region formed. While the maximum elongation occurred at the strain rate of 5×10-2 s-1 in ECAPed UFG alloy, it took place at lower strain rate of 1×10-2 s-1 after aging for all time periods. Also, flow stress of the alloy increased with increasing grain size during natural aging. © 2016 Trans Tech Publications, Switzerland.Öğe Effect of resin content on tribological behavior of brake pad composite material(Emerald Group Publishing Ltd., 2018) Yanar H.; Ayar H.H.; Demirtas M.; Purcek G.Purpose: This paper aims to investigate the effect of straight phenolic resin content on the fade behavior, frictions and wear characteristics of pre-determined brake pad composite matrix having specific amount of barite (BaSO4), rock wool, Kevlar, graphite and magnetite. Design/methodology/approach: Different amount of resin ranging between 16 and 20 wt. per cent were added by changing only the filler (barite) content of composite matrix. Subsequently, friction and wear behavior of the composite samples were analyzed using a special pin-on-disc type test system developed for brake pad sample. The worn surfaces were investigated by SEM and three-dimensional (3D) surface profilometer. Findings: The average coefficient of friction (CoF) of composite samples and temperature of the disc surface showed a linear increase with decreasing the resin content. The sample having 20 wt. per cent resin showed the minimum wear rate with smooth worn surface. But the amount of fade is quite high in that sample. Decreasing resin content decreased the fade formation, and the composite with 16 per cent resin brought about the minimum fade formation. As the fade formation is unwanted in brake pad applications, the composite with 16 wt. per cent resin was proposed as the most appropriate one considering the performance parameters related to friction and wear. Originality/value: This paper optimizes the resin content of composite brake pad materials to achieve the best combination of its tribo-performance and mechanical properties and provides valuable information for scientists and engineers working in that area. © 2018, Emerald Publishing Limited.Öğe Effects of grain size on room temperature deformation behavior of Zn–22Al alloy under uniaxial and biaxial loading conditions(Elsevier Ltd, 2016) Cetin M.E.; Demirtas M.; Sofuoglu H.; Cora Ö.N.; Purcek G.Effects of grain size on room temperature (RT) deformation behavior of superplastic Zn–22Al alloy under uniaxial and biaxial loading conditions were investigated. Two–step equal channel angular pressing (ECAP) and subsequent annealing processes were applied to the alloy in order to obtain microstructures with various grain sizes ranging from submicron to micron sizes. Grain size of 200 nm was achieved after ECAP of the alloy, and it was increased up to ~2.60 µm by annealing at 250 °C for different time periods. Changes in deformation behaviors of the alloy with various grain sizes were found to be in good agreement under the uniaxial tensile and biaxial Erichsen test conditions. Increasing grain size decreased both the maximum elongation under uniaxial deformation and limiting dome height (LDH) under biaxial deformation. The high elongation to failure and LDH values for the samples with submicron grain size were attributed to their high strain rate sensitivity. © 2016 Elsevier B.V.Öğe Enhancing the Damping Behavior of Dilute Zn-0.3Al Alloy by Equal Channel Angular Pressing(Springer Boston, 2017) Demirtas M.; Atli K.C.; Yanar H.; Purcek G.The effect of grain size on the damping capacity of a dilute Zn-0.3Al alloy was investigated. It was found that there was a critical strain value (?1 × 10 ?4 ) below and above which damping of Zn-0.3Al showed dynamic and static/dynamic hysteresis behavior, respectively. In the dynamic hysteresis region, damping resulted from viscous sliding of phase/grain boundaries, and decreasing grain size increased the damping capacity. While the quenched sample with 100 to 250 µm grain size showed very limited damping capacity with a loss factor tan? of less than 0.007, decreasing grain size down to 2 µm by equal channel angular pressing (ECAP) increased tan? to 0.100 in this region. Dynamic recrystallization due to microplasticity at the sample surface was proposed as the damping mechanism for the first time in the region where the alloy showed the combined aspects of dynamic and static hysteresis damping. In this region, tan? increased with increasing strain amplitude, and ECAPed sample showed a tan? value of 0.256 at a strain amplitude of 2 × 10 ?3 , the highest recorded so far in the damping capacity-related studies on ZA alloys. © 2017, The Minerals, Metals & Materials Society and ASM International.Öğe High temperature superplasticity and deformation behavior of naturally aged Zn-Al alloys with different phase compositions(Elsevier Ltd, 2018) Demirtas M.; Kawasaki M.; Yanar H.; Purcek G.Two Zn-Al alloys, eutectoid Zn-22Al and dilute Zn-0.3Al, were processed through equal-channel angular pressing (ECAP). The ECAP-processed alloys were subjected to long-term natural aging at room temperature for 120 days in order to investigate the effect of long-term natural aging on high-temperature superplasticity and the deformation behavior of these alloys. The grain size of the Zn-22Al alloy increased from 200 nm after ECAP to 400 nm after the natural aging process. The Zn-0.3Al alloy with a grain size of 1.3 µm after ECAP demonstrated a reasonably stable microstructure with the grain size of ~ 1.7 µm after long-term natural aging. The naturally aged ultrafine-grained (UFG) Zn-22Al alloy showed an excellent superplastic elongation of about 1800% at 200 °C. Grain boundary sliding was determined as the dominant deformation mechanism in this alloy. On the contrary, a considerably low elongation to failure of 230% was recorded in the naturally aged fine-grained (FG) Zn-0.3Al alloy at 150 °C, and dislocation creep was evaluated as the main deformation mechanism for this alloy. Detailed microstructural analyses showed that the FG Zn-0.3Al alloy was exposed to grain boundary corrosion during the natural aging process due to the presence of Al precipitates at grain boundaries whereas such formation was not observed in the UFG Zn-22% Al alloy. Grain boundary sliding was hindered by grain boundary corrosion and the cavity nucleation at the corroded grain boundaries caused a premature failure leading to such a low elongation in the Zn-0.3Al alloy. © 2018 Elsevier B.V.Öğe Improvement of high strain rate and room temperature superplasticity in Zn-22Al alloy by two-step equal-channel angular pressing(Elsevier Ltd, 2014) Demirtas M.; Purcek G.; Yanar H.; Zhang Z.J.; Zhang Z.F.The Zn-22Al alloy was subjected to equal-channel angular pressing (ECAP) to improve its high strain rate (HSR) superplasticity at room temperature (RT). A well-designed two-step ECAP process formed an ultrafine-grained (UFG) microstructure with an average grain size of 200nm as the lowest one obtained so far after ECAP processing of this alloy. Also, agglomerate- and texture-free microstructure with UFG Al-rich ?- and Zn-rich ?-grains separated mostly by high-angle grain boundaries (HAGBs) was produced by this process. The maximum RT elongation was achieved to be 400% with a strain rate sensitivity of 0.30 at a very high strain rate of 5×10-2s-1 after the two-step ECAP process. This elongation value is the highest one obtained at RT and at all strain rates for this alloy up to now. The current results demonstrate that such an improvement in superplasticity of Zn-22Al alloy after the two-step ECAP process can enhance its applications where RT and HSR superplasticity are strongly needed. © 2014 Elsevier B.V.Öğe Influence of high pressure torsion-induced grain refinement and subsequent aging on tribological properties of Cu-Cr-Zr alloy(Elsevier Ltd, 2018) Purcek G.; Yanar H.; Shangina D.V.; Demirtas M.; Bochvar N.R.; Dobatkin S.V.Effects of ultrafine grain formation via high pressure torsion (HPT) and precipitation during aging on the microstructure, mechanical and tribological properties of a Cu-Cr-Zr alloy have been investigated systematically. HPT results in the formation of ultrafine-grained (UFG) structure in the alloy with an average grain/subgrain size of 155 nm which leads to remarkable improvement in its hardness and strength along with a reduction in elongation to failure. Aging of UFG alloy brings about further strengthening due to the precipitation. UFG formation by HPT increases substantially the wear resistance of Cu-Cr-Zr alloy and reduces the friction coefficient. The highest wear resistance and the lowest friction coefficient are obtained on the sample processed by HPT and subsequent aging. The dominant wear mechanism of the alloy varies depending on the applied processes. Adhesion with smearing is the predominant wear mechanism for the initial (warm extruded) samples having coarse-grained (CG) structure. UFG samples show less adhesional effect with less smearing, and a higher tendency to the formation of cracks, abrasion and delamination seem to be dominant in those samples. Oxidative wear mechanism is also operative in both CG and UFG alloy samples. It may be concluded from this study that a combined process including UFG formation by HPT and subsequent precipitation by artificial aging provides a simple and effective processing procedure for improving the strength, hardness and wear resistance of Cu–Cr–Zr alloys without modification of the chemical composition. © 2018 Elsevier B.V.Öğe Optimization of RT superplasticity of UFG Zn-22Al alloy by applying ECAP at different temperatures and phase regions(Institute of Physics Publishing, 2017) Demirtas M.; Yanar H.; Purcek G.Zn-22Al alloy was subjected to either one-step or two-step equal channel pressing (ECAP) to investigate the effect of processing temperature on its microstructure and room temperature (RT) superplasticity. In one-step ECAP processes, 4 passes ECAP were applied to the alloy at different temperatures: RT, 100°C and 250°C in two-phase region below eutectoid temperature and 350°C in single-phase region above eutectoid temperature. In two-step ECAP processes, one-step ECAP-processed samples were subjected to four more passes ECAP at RT. Considering the one-step ECAP processing, RT superplasticity increased with decreasing ECAP temperature as expected, and the highest RT superplasticity was achieved as 350% after 4 passes ECAP at RT. On the other hand, application of 4 more passes ECAP at RT to the sample showing the lowest superplastic elongation after one-step ECAP (the sample processed at 350°C) resulted in the maximum RT elongation of 400% at a high strain rate of 5×10-2 s-1. These results suggest that first step temperature of two-step ECAP process is needed to increase above the eutectoid point of Zn-22Al alloy to achieve high RT superplasticity. These results were attributed to the changes in microstructure inside the single-phase and two-phase regions during the processes. © Published under licence by IOP Publishing Ltd.Öğe Optimization of strength, ductility and electrical conductivity of Cu-Cr-Zr alloy by combining multi-route ECAP and aging(Elsevier Ltd, 2016) Purcek G.; Yanar H.; Demirtas M.; Alemdag Y.; Shangina D.V.; Dobatkin S.V.Properties of Cu-Cr-Zr alloy with ultrafine-grained (UFG) structure produced by equal-channel angular pressing (ECAP) via different routes have been investigated. Special attention was paid to the optimization of multi-functional structural, thermal, electrical and mechanical properties of the alloy by aging of UFG one. Multi-pass ECAP via different routes gives rise to the formation of a deformation-induced submicrocrystalline structure with the grain (subgrain) sizes in the range of 200-300. nm depending on applied routes which leads to high hardness and strength in the Cu-Cr-Zr alloy with reduced ductility. Amongst the applied routes, route-Bc was found to be the best processing path for achieving the lowest grain size, the highest hardness and strength. Aging of 8Bc-processed UFG samples increases the hardness and strength of Cu-Cr-Zr alloy while retaining an electrical conductivity comparable to that of aged coarse-grained (CG) one. A satisfactory electrical conductivity of 71%IACS without considerable loss of peak hardness was achieved after aging of 8Bc-processed UFG alloy at 425. °C for 240. min. The precipitation strengthened UFG alloy remains its stable behavior at elevated temperatures up to 450. °C. © 2015 Elsevier B.V.Öğe Room temperature superplasticity in fine/ultrafine-grained Zn-Al alloys with different phase compositions(Trans Tech Publications Ltd, 2018) Demirtas M.; Yanar H.; Saray O.; Purcek G.Three Zn-Al alloys, namely Zn-22Al, Zn-5Al and Zn-0.3Al, were subjected to equal-channel angular pressing (ECAP), and the effect of ECAP on their microstructure and room temperature (RT) superplastic behavior were investigated in detail referring to previous studies reported by the authors of the current study. ECAP remarkably refined the microstructures of three alloys as compared to their pre-processed conditions. While the lowest grain size was achieved in Zn-22Al alloy as 200 nm, the grain sizes of Zn-5Al and Zn-0.3Al alloys were ~540 nm and 2 µm, respectively, after ECAP. After the formation of fine/ultrafine-grained (F/UFG) microstructures, all Zn-Al alloys exhibited superplastic behavior at RT and high strain rates. The maximum superplastic elongations were 400%, 520% and 1000% for Zn-22Al, Zn-5Al and Zn-0.3Al alloys, respectively. It is interesting to point out that the highest RT superplastic elongation was obtained in Zn-0.3Al alloy with the largest grain size, while Zn-22Al alloy having the lowest grain size showed the minimum superplastic elongation. This paradox was attributed to the different phase compositions of these alloys. The formation of Al-rich ?/? phase boundaries, where grain boundary sliding is minimum comparing to Zn-rich ?/? and ?/? phase boundaries of Zn-Al alloys, is the lowest level in Zn-0.3Al alloy among all the alloys. Therefore, it can be concluded that if it is desired to achieve high superplastic elongation in Zn-Al alloys at RT, keeping Al content at a possibly minimum level seems to be the most suitable way. © 2018 Trans Tech Publications, Switzerland
