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Öğe DETERMINATION OF PARAMETERS AFFECTING KINETIC AND THERMODYNAMIC VALUES FOR LEAD REMOVAL USING WASTEWATER TREATMENT PLANT SEWAGE SLUDGE ASH(Chem Soc Ethiopia, 2022) Irdemez, Sahset; Yesilyurt, Duygu; Torun, Fatma Ekmekyapar; Kul, SinanIn this study, treatment of lead containing wastewater using sewage sludge ash obtained from the incineration unit in the domestic wastewater treatment plant in Gaziantep province in Turkey was investigated. The main purpose of the study is to determine the potential of using the treatment sludge ash, which comes out as waste in the treatment plant, in the treatment of wastewater of another industry. As a result of this study, the most suitable adsorption conditions were determined and focused on the kinetics of adsorption. In the experiments, the lead adsorption capacity of sewage sludge ash was determined as 122 mg g-1 at 0.5 g L-1 adsorbent concentration in wastewater containing 100 mg L-1 Pb2+under optimum conditions. As a result of the research, it was determined that the adsorption reaction proceeds according to the pseudo second degree reaction and is suitable for the Langmuir isotherm. As thermodynamic constants, & UDelta;H & DEG; = 7.407 kJ mol-1 and & UDelta;S & DEG; = 33.25 J mol-1 were determined. As a result of this, it was determined that the adsorption reaction was endothermic, spontaneous and random, and adsorption was physical adsorption. The results show that sewage sludge ash can be used in the treatment of water containing high concentrations of Pb2+.Öğe Investigation of Manganese Ion Removal from Waters Using Sewage Sludge Ash(Jihad Daneshgahi, 2022) Irdemez, Sahset; Yesilyurt, Duygu; Torun, Fatma Ekmekyapar; Kul, Sinan; Bingul, ZuleyhaIn this study, the removal of Mn2+ ions from waters by the adsorption method using ash obtained from a treatment plant sludge burning unit, which is treatment plant waste and mostly disposed of in a landfill, was investigated. By determining the most suitable conditions for adsorption, adsorption kinetics, isotherms, and thermodynamic values were determined. In the experiments, 63.9% removal efficiency was achieved using 10 g/L adsorbent concentration for 10 mg/L Mn+2 under optimum conditions. As a result of the research, it was determined that the adsorption proceeds according to the pseudo-second-degree reaction and abides by the Langmuir isotherm. The thermodynamic constants of Delta H degrees= -4.866 kJ/mol and Delta S degrees= 21.44 J/mol were determined. As a result of this, the reaction was exothermic, spontaneous, and random, and adsorption was physical adsorption. As a result of the study, sewage sludge ash can be used in the treatment of water containing low concentrations of Mn2+ .