Asymmetric Friedel-Crafts alkylation of pyrrole with nitroalkenes catalyzed by a copper complex of a bisphenol A-derived Schiff base

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dc.authorid57195975748
dc.authorid37098938400
dc.authorid8276939300
dc.authorid57197789938
dc.contributor.authorÖzdemir H.S.
dc.contributor.authorŞahin E.
dc.contributor.authorÇakici M.
dc.contributor.authorKiliç H.
dc.date.accessioned20.04.201910:49:12
dc.date.accessioned2019-04-20T21:43:50Z
dc.date.available20.04.201910:49:12
dc.date.available2019-04-20T21:43:50Z
dc.date.issued2015
dc.departmentBayburt Üniversitesien_US
dc.description.abstractThe asymmetric Friedel-Crafts (FC) alkylation of pyrrole with nitroalkenes was mediated by CuBr2 and a novel bisphenol A-derived chiral catalyst at room temperature. The catalyst was found to be applicable for the asymmetric FC alkylation of pyrrole with a wide range of nitroalkenes, affording optically active alkylated pyrroles with enantioselectivities up to 94%. Furthermore, enantiomerically pure 3-nitro-2-arylpropanamides were prepared by the oxidative cleavage of the pyrrole rings in the FC products with NaIO4/RuCl3 to demonstrate the synthetic application of the products. © 2015 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.tet.2015.03.059
dc.identifier.endpage2890
dc.identifier.issn0040-4020
dc.identifier.issue19
dc.identifier.scopus2-s2.0-84937763901en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2882
dc.identifier.urihttps://dx.doi.org/10.1016/j.tet.2015.03.059
dc.identifier.urihttps://hdl.handle.net/20.500.12403/696
dc.identifier.volume71
dc.identifier.wosWOS:000353610700009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Ltd
dc.relation.ispartofTetrahedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAsymmetric Friedel-Crafts alkylation
dc.subjectAsymmetric synthesis
dc.subjectChiral copper complex
dc.subjectNitroalkene
dc.subjectPyrrole
dc.subjectAsymmetric Friedel-Crafts alkylation
dc.subjectAsymmetric synthesis
dc.subjectChiral copper complex
dc.subjectNitroalkene
dc.subjectPyrrole
dc.titleAsymmetric Friedel-Crafts alkylation of pyrrole with nitroalkenes catalyzed by a copper complex of a bisphenol A-derived Schiff baseen_US
dc.typeArticleen_US

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