Synthesis, characterization and complexation properties of a novel Mg-porphyrazine with metal ions in acetonitrile-chloroform

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dc.authorid9251050200
dc.authorid55388209500
dc.authorid7005138866
dc.authorid56440284900
dc.authorid6506636234
dc.contributor.authorKabay N.
dc.contributor.authorBaygu Y.
dc.contributor.authorGök Y.
dc.contributor.authorBaşo?lu A.
dc.contributor.authorOcak U.
dc.date.accessioned20.04.201910:49:12
dc.date.accessioned2019-04-20T21:44:03Z
dc.date.available20.04.201910:49:12
dc.date.available2019-04-20T21:44:03Z
dc.date.issued2015
dc.departmentBayburt Üniversitesien_US
dc.description.abstractThe synthesis and characterization of a novel metal derivative of a peripherally symmetrically tetra-substituted porphyrazine derived from 25,26-dioxa-6,7,9,10,15,16,18,19-octahydro-25H-1,24-methanodibenzo[q,t][1,4,13,16,17,10]tetraoxadithiacyclohenicosine-12,13-dicarbonitrile was carried out. The influence of metal cations such as Zn2+, Fe2+, Mn2+, Ni2+, Co2+, Hg2+ and Cu2+ on the spectroscopic properties of the ligands, the starting material dinitrile and MgPz were investigated in acetonitrile-chloroform solution (1/1) by means of absorption spectrometry. Absorption spectra showed isosbestic points in the spectrophotometric titration of Cu2+ and Hg2+ with MgPz ligand. The results of spectrophotometric titration experiments disclosed the complex stability constant of the novel ligand, MgPz with Cu2+ and Hg2+ cations.en_US
dc.identifier.doi10.3233/MGC-140148
dc.identifier.endpage11
dc.identifier.issn1024-1221
dc.identifier.issue1
dc.identifier.scopus2-s2.0-84915750804en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage1
dc.identifier.urihttps://dx.doi.org/10.3233/MGC-140148
dc.identifier.urihttps://hdl.handle.net/20.500.12403/755
dc.identifier.volume14
dc.identifier.wosWOS:000345980500001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherIOS Press
dc.relation.ispartofMain Group Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectabsorption spectroscopy
dc.subjectCrown ether
dc.subjectmetal cation
dc.subjectporphyrazine
dc.subjectstability constant
dc.subjectabsorption spectroscopy
dc.subjectCrown ether
dc.subjectmetal cation
dc.subjectporphyrazine
dc.subjectstability constant
dc.titleSynthesis, characterization and complexation properties of a novel Mg-porphyrazine with metal ions in acetonitrile-chloroformen_US
dc.typeArticleen_US

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