Electrical, Magnetic, Microstructural, and Characteristic Properties of Zirconium-Substituted Co0.5Ni0.5ZrxFe2-xO4Spinel Ferrite Nanostructures

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dc.authoridTEBER, AHMET/0000-0002-7361-2302
dc.authoridSarac, Mehmet Fahri/0000-0002-0760-5569
dc.contributor.authorTeber, Ahmet
dc.contributor.authorSarac, Mehmet F.
dc.date.accessioned2024-10-04T18:49:42Z
dc.date.available2024-10-04T18:49:42Z
dc.date.issued2023
dc.departmentBayburt Üniversitesien_US
dc.description.abstractThe effect of zirconium (Zr) substitution in nickel-cobalt ferrites, Co0.5Ni0.5ZrxFe2-xO4 (0.0 <= x <= 1.0) produced by the hydrothermal method on the electrical, magnetic, microstructural and characteristic properties are reported. A secondary phase as tetragonal-ZrO2 phase in the crystal system is detected and have both M-type hexagonal and tetragonal nanocrystallites between 32 and 67 nm. Refined structural parameters using Rietveld analysis are carried out, resulting in lattice parameters, the unit cell volume, parameter ratios, and the crystallite size using the TOPAS refinement program. In addition, residuals for the R-Bragg factor and goodness of fit (chi(2)) value for each concentration are represented. The Rietveld analysis determines that the predicted and actual diffraction patterns are in accord. Furthermore, the Zr effect is presented in unit volume as seen by the drop in peak intensity that occurs (with the addition of Zr) due to the lattice tension. Moreover, the morphological analyses indicate that the shape transformed from agglomerated clusters to oval-shaped structures and a reduction in grain size. Fourier transform infrared (FT-IR) analysis in the range of 4000-450 cm(-1) correlates with the presence of the hexagonal spinel ferrite structure. The dielectric parameters, such as the relative permittivity, tangent loss, and ac conductivity, are experimentally measured with the oscillation voltage level of 0.05 V in the frequency range of 0.1-10 MHz. The dielectric permittivities and tangent losses of the specimens decreased with an increment in frequency. Magnetic measurements reveal that the values of coercivity (H-c) have the propensity to increase relating to the zirconium concentration.en_US
dc.identifier.doi10.1007/s13369-023-07607-0
dc.identifier.endpage8164en_US
dc.identifier.issn2193-567X
dc.identifier.issn2191-4281
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85146135324en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage8153en_US
dc.identifier.urihttps://doi.org/10.1007/s13369-023-07607-0
dc.identifier.urihttp://hdl.handle.net/20.500.12403/3261
dc.identifier.volume48en_US
dc.identifier.wosWOS:000910641200001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofArabian Journal For Science and Engineeringen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectZirconium substitutionen_US
dc.subjectM-type hexagonal ferritesen_US
dc.subjectHydrothermal methoden_US
dc.subjectMagneticen_US
dc.subjectelectrical propertiesen_US
dc.subjectNanoparticlesen_US
dc.titleElectrical, Magnetic, Microstructural, and Characteristic Properties of Zirconium-Substituted Co0.5Ni0.5ZrxFe2-xO4Spinel Ferrite Nanostructuresen_US
dc.typeArticleen_US

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