Conjugated polythiophene/Ni doped ZnO hetero bilayer nanocomposite thin films: Its structural, optical and photoluminescence properties
Küçük Resim Yok
Tarih
2018
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, synthesis and characterization of plasma polymerized Thiophene/ Nickel doped Zinc Oxide (PTNZO) bilayer nanocomposite films were carried out. Nickel doped zinc oxide (NZO) thin films were obtained by magnetron sputtering technique on glass substrates at 40 W Radio Frequency (RF) power. Plasma polymerized Thiophene (PT) thin films were deposited on the NZO thin films obtained on the glass substrate by Radio Frequency (RF) plasma polymerisation technique. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), FTIR and Photoluminescence (PL) analyzes were performed for the characterization of PTNZO hetero bilayer nanocomposite films. In the XRD spectra of PTNZO bilayer nanocomposite thin films, (002) planes were determined as the most basic peak, and it was determined that the intensity of this peak, changed depending on the RF power of polymer thin films. Optical properties of nanocomposite thin films such as transmittance, absorbance and optical band gap were determined by UV–Vis spectroscopy. Optical band gap for PTNZO nanocomposites were 2.72 eV, 2.34 eV, and 2.45 eV, respectively, with increasing RF power. For NZO thin films, this value is 3.12 eV. The optical band gaps calculated from the absorption and transmittance spectra obtained using UV–visible spectroscopy had a good compatibility with those of the optical band spectra calculated from the PL spectra. The tetragonal wurtzite structure of the NZO thin films was examined by SEM analysis. The grain size of NZO nanostructure was found to be approximately 59 nm. © 2018 Elsevier Ltd and Techna Group S.r.l.
Açıklama
Anahtar Kelimeler
Bilayer nanocomposite, Conjugated polymers, Thiophene, Wurtzite structure, ZnO, Conjugated polymers, Energy gap, Fourier transform infrared spectroscopy, Glass, II-VI semiconductors, Nanocomposite films, Nanocomposites, Nickel oxide, Optical band gaps, Optical properties, Oxide films, Photoluminescence, Plasma polymerization, Polymer films, Radio waves, Scanning electron microscopy, Substrates, Thin films, Thiophene, X ray diffraction, Zinc oxide, Zinc sulfide, Bi-layer, Nanocomposite thin films, Photoluminescence properties, Radio frequency plasma, Radio frequency power, Synthesis and characterizations, Transmittance spectra, Wurtzite structure, Optical films, Bilayer nanocomposite, Conjugated polymers, Thiophene, Wurtzite structure, ZnO, Conjugated polymers, Energy gap, Fourier transform infrared spectroscopy, Glass, II-VI semiconductors, Nanocomposite films, Nanocomposites, Nickel oxide, Optical band gaps, Optical properties, Oxide films, Photoluminescence, Plasma polymerization, Polymer films, Radio waves, Scanning electron microscopy, Substrates, Thin films, Thiophene, X ray diffraction, Zinc oxide, Zinc sulfide, Bi-layer, Nanocomposite thin films, Photoluminescence properties, Radio frequency plasma, Radio frequency power, Synthesis and characterizations, Transmittance spectra, Wurtzite structure, Optical films
Kaynak
Ceramics International
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
44
Sayı
17
