Complexation of metal ions with double-armed diazadithia lariat ether carrying anthracene moieties in acetonitrile-dioxane

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dc.authorid25936626900
dc.authorid25935836500
dc.authorid36672793600
dc.authorid6507422386
dc.authorid7003387211
dc.authorid56284385000
dc.authorid6506636234
dc.contributor.authorParlayan S.
dc.contributor.authorBaşo?lu A.
dc.contributor.authorGöbel Y.
dc.contributor.authorOcak M.
dc.contributor.authorAlp H.
dc.contributor.authorKantekin H.
dc.contributor.authorOcak Ü.
dc.date.accessioned20.04.201910:49:12
dc.date.accessioned2019-04-20T21:44:52Z
dc.date.available20.04.201910:49:12
dc.date.available2019-04-20T21:44:52Z
dc.date.issued2010
dc.departmentBayburt Üniversitesien_US
dc.description.abstractA new 14-membered crown ether with nitrogen-sulfur donor atom carrying two anthryl groups was designed and synthesized by the reaction of the corresponding macrocyclic compound and 9-(chloromethyl) anthracene. The influence of metal cations such as Al3+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Cd2+, Hg2+ and Pb2+ on the spectroscopic properties of the ligand was investigated in acetonitrile-dioxane solution (1/1) by means of absorption and emission spectrometry. The results of spectrophotometric titration experiments disclosed the complexation stoichiometry and complex stability constant of the novel ligand with Fe2+, Fe3+, Al3+, Cd2+, Cu2+, Zn2+, Pb2+ and Hg2+ cations. Absorption spectra show isobestic points in the spectrophotometric titration of these cations. The presence of excess of Al3+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Cd2+, Hg2+ and Pb2+ cations caused an enhancement of anthryl fluorescence. Especially, the enhancement in case of the interaction of Hg2+ and Al3+ cations with the ligand was pronounced. © Springer Science+Business Media B.V. 2010.en_US
dc.identifier.doi10.1007/s10847-009-9728-1
dc.identifier.endpage460
dc.identifier.issn0923-0750
dc.identifier.issue3
dc.identifier.scopus2-s2.0-77952878562en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage451
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-009-9728-1
dc.identifier.urihttps://hdl.handle.net/20.500.12403/959
dc.identifier.volume67
dc.identifier.wosWOS:000277958600024en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject9-(chloromethyl) anthracene
dc.subjectCrown ether
dc.subjectFluorescence spectroscopy
dc.subjectMetal cation
dc.subjectStability constant
dc.subject9-(chloromethyl) anthracene
dc.subjectCrown ether
dc.subjectFluorescence spectroscopy
dc.subjectMetal cation
dc.subjectStability constant
dc.titleComplexation of metal ions with double-armed diazadithia lariat ether carrying anthracene moieties in acetonitrile-dioxaneen_US
dc.typeArticleen_US

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