Hydrogen generation via the catalytic hydrolysis of morpholine-borane: A new, efficient and cost-effective hydrogen storage medium

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dc.authoridMetin, Onder/0000-0003-1622-4992
dc.contributor.authorCan, Hasan
dc.contributor.authorMetin, Onder
dc.date.accessioned2024-10-04T18:51:05Z
dc.date.available2024-10-04T18:51:05Z
dc.date.issued2019
dc.departmentBayburt Üniversitesien_US
dc.description.abstractHerein, for the first time, we introduce the morpholine-borane complex (MB) as a new, efficient, cost-effective and commercially available chemical hydrogen storage material for mobile applications. In this regard, hydrogen production from the hydrolysis of MB catalyzed by in situ generated water-soluble polymer stabilized Ag(0) and Pd(0) nanoparticles (NPs) is reported for the first time. In situ generated PSMA-stabilized Ag(0) and Pd(0) NPs showed remarkable activity in hydrogen production from the hydrolysis of MB at room temperature, providing initial TOFs of 16.1 min(-1) and 37.3 min(-1), respectively. A set of kinetic studies on the catalytic hydrolysis of MB were conducted by changing the catalyst/substrate amount and temperature, and the rate law expression and activation parameters were produced by collecting the kinetic data. The apparent activation energies for the in situ generated Ag(0) and Pd(0) NPs catalyzed MB hydrolysis were calculated to be 71.4 and 32.5 kJ mol(-1), respectively. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipTUBITAK [116Z226]en_US
dc.description.sponsorshipThe authors would like to thank TUBITAK for the financial support under the contract number of 116Z226.en_US
dc.identifier.doi10.1016/j.ijhydene.2019.08.043
dc.identifier.endpage25651en_US
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue47en_US
dc.identifier.scopus2-s2.0-85071639777en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage25642en_US
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2019.08.043
dc.identifier.urihttp://hdl.handle.net/20.500.12403/3375
dc.identifier.volume44en_US
dc.identifier.wosWOS:000490030000029en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofInternational Journal of Hydrogen Energyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMorpholine boraneen_US
dc.subjectHydrogen storageen_US
dc.subjectHydrogen productionen_US
dc.subjectHydrolysisen_US
dc.subjectMetal nanoparticlesen_US
dc.subjectNanocatalysisen_US
dc.titleHydrogen generation via the catalytic hydrolysis of morpholine-borane: A new, efficient and cost-effective hydrogen storage mediumen_US
dc.typeArticleen_US

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