Tailoring the optoelectronic properties of ZnO nanowires via TiO2 coating
Küçük Resim Yok
Tarih
2025
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Indian Assoc Cultivation Science
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The photosensing properties of TiO2/ZnO nanowires (NWs) were investigated by sequential deposition using thermal oxidation and sol-gel. It was found that TiO2/ZnO NWs with 5 mM concentration exhibit a higher aspect ratio compared to the 10 mM and 25 mM TiO2/ZnO NWs. The surface-to-volume ratio directly influences the photoluminescence (PL) intensity and electrical properties of the ZnO NWs. XPS confirmed the presence of TiO2 on the surface, while EDS detected titanium, with its concentration increasing as the TiO2 concentration rises. The photosensing performance of ZnO has been significantly improved by modifying it with TiO2. However, determining the optimum concentration is a critical factor in performance improvement. The findings show that high TiO2 concentrations improve surface properties, but excessive coating may limit carrier mobility. Photosensitivity has been increased at lower TiO2 concentration due to a higher surface-to-volume ratio (SVR) and, as a result, higher surface photoactivity. The 25 mM TiO2/ZnO NW array stands out in optimal detectability and photoresponsivity due to the reduced resistance caused by the increased Ti concentration on the surface. The 25 mM TiO2/ZnO NWs achieved the highest photoresponsivity (717 mA/W) and specific detectivity (1.48 x 101 degrees Jones), while the 5 mM TiO2/ZnO NWs exhibited exceptional photosensitivity (320.11%), making them ideal for UV detection. The samples at varying concentrations show promise in photosensitivity, detectability, and photoresponsivity, making them suitable for environmental sensors, UV detectors, and other optoelectronic applications.
Açıklama
Anahtar Kelimeler
Titanium dioxide, Zinc oxide, Electrical properties, Optical properties, Semiconductor
Kaynak
Indian Journal of Physics
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
99
Sayı
14
