Synthesis and electrochemistry of metallophthalocyanines bearing {4-[(2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl]phenoxy} groups
Küçük Resim Yok
Tarih
2014
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, metallophthalocyanines 4, 5, 6 was carried out by the cyclotetramerization of 4-{3-[(2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl] phenoxy}phthalonitrile 3. The synthesis of metallo derivatives [Zn(II), Co(II), Cu(II)] of phthalocyanines obtained from corresponding phthalonitrile derivative and in the presence of the anhydrous divalent metal salts (Zn(CH 3COO)2, CoCl2 and CuCl2) was described. These phthalocyanines showed good solubility in organic solvents such as chloroform, tetrahydrofuran, DMSO and DMF. The newly synthesized Pcs were verified by IR, 1H NMR, 13C NMR, UV-vis and MS spectral data. The electrochemical properties of the zinc(II), copper(II) and cobalt(II) phthalocyanines were investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. The cobalt complex showed a metal based reduction process, while zinc phthalocyanines were giving ligand based electron transfer processes. © 2013 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Cyclic voltammetry, Differential pulse voltammetry, Metallophthalocyanine, Microwave, Phthalocyanine, Zinc, Cobalt phthalocyanine, Cyclotetramerization, Differential pulse voltammetry, Divalent metal salts, Electron transfer process, Metallophthalocyanines, Phthalocyanine, Zinc phthalocyanines, Cobalt, Cobalt compounds, Cyclic voltammetry, Microwaves, Nitrogen compounds, Nuclear magnetic resonance spectroscopy, Organic solvents, Zinc, Zinc compounds, Copper, Cyclic voltammetry, Differential pulse voltammetry, Metallophthalocyanine, Microwave, Phthalocyanine, Zinc, Cobalt phthalocyanine, Cyclotetramerization, Differential pulse voltammetry, Divalent metal salts, Electron transfer process, Metallophthalocyanines, Phthalocyanine, Zinc phthalocyanines, Cobalt, Cobalt compounds, Cyclic voltammetry, Microwaves, Nitrogen compounds, Nuclear magnetic resonance spectroscopy, Organic solvents, Zinc, Zinc compounds, Copper
Kaynak
Journal of Organometallic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
752
