Synthesis and electrochemistry of metallophthalocyanines bearing {4-[(2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl]phenoxy} groups

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dc.authorid6507022942
dc.authorid35738432100
dc.authorid7007068765
dc.authorid7005590316
dc.authorid55984363300
dc.authorid23100981600
dc.contributor.authorAcar I.
dc.contributor.authorArslan T.
dc.contributor.authorTopçu S.
dc.contributor.authorAktaş A.
dc.contributor.authorŞen S.
dc.contributor.authorSerencam H.
dc.date.accessioned20.04.201910:49:12
dc.date.accessioned2019-04-20T21:44:11Z
dc.date.available20.04.201910:49:12
dc.date.available2019-04-20T21:44:11Z
dc.date.issued2014
dc.departmentBayburt Üniversitesien_US
dc.description.abstractIn this study, metallophthalocyanines 4, 5, 6 was carried out by the cyclotetramerization of 4-{3-[(2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl] phenoxy}phthalonitrile 3. The synthesis of metallo derivatives [Zn(II), Co(II), Cu(II)] of phthalocyanines obtained from corresponding phthalonitrile derivative and in the presence of the anhydrous divalent metal salts (Zn(CH 3COO)2, CoCl2 and CuCl2) was described. These phthalocyanines showed good solubility in organic solvents such as chloroform, tetrahydrofuran, DMSO and DMF. The newly synthesized Pcs were verified by IR, 1H NMR, 13C NMR, UV-vis and MS spectral data. The electrochemical properties of the zinc(II), copper(II) and cobalt(II) phthalocyanines were investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. The cobalt complex showed a metal based reduction process, while zinc phthalocyanines were giving ligand based electron transfer processes. © 2013 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2013.11.021
dc.identifier.endpage29
dc.identifier.issn0022-328X
dc.identifier.scopus2-s2.0-84891587020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage25
dc.identifier.urihttps://dx.doi.org/10.1016/j.jorganchem.2013.11.021
dc.identifier.urihttps://hdl.handle.net/20.500.12403/790
dc.identifier.volume752
dc.identifier.wosWOS:000330119900005en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyclic voltammetry
dc.subjectDifferential pulse voltammetry
dc.subjectMetallophthalocyanine
dc.subjectMicrowave
dc.subjectPhthalocyanine
dc.subjectZinc
dc.subjectCobalt phthalocyanine
dc.subjectCyclotetramerization
dc.subjectDifferential pulse voltammetry
dc.subjectDivalent metal salts
dc.subjectElectron transfer process
dc.subjectMetallophthalocyanines
dc.subjectPhthalocyanine
dc.subjectZinc phthalocyanines
dc.subjectCobalt
dc.subjectCobalt compounds
dc.subjectCyclic voltammetry
dc.subjectMicrowaves
dc.subjectNitrogen compounds
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectOrganic solvents
dc.subjectZinc
dc.subjectZinc compounds
dc.subjectCopper
dc.subjectCyclic voltammetry
dc.subjectDifferential pulse voltammetry
dc.subjectMetallophthalocyanine
dc.subjectMicrowave
dc.subjectPhthalocyanine
dc.subjectZinc
dc.subjectCobalt phthalocyanine
dc.subjectCyclotetramerization
dc.subjectDifferential pulse voltammetry
dc.subjectDivalent metal salts
dc.subjectElectron transfer process
dc.subjectMetallophthalocyanines
dc.subjectPhthalocyanine
dc.subjectZinc phthalocyanines
dc.subjectCobalt
dc.subjectCobalt compounds
dc.subjectCyclic voltammetry
dc.subjectMicrowaves
dc.subjectNitrogen compounds
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectOrganic solvents
dc.subjectZinc
dc.subjectZinc compounds
dc.subjectCopper
dc.titleSynthesis and electrochemistry of metallophthalocyanines bearing {4-[(2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl]phenoxy} groupsen_US
dc.typeArticleen_US

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